Tantalum pentachloride-methylene chloride system performs C-C and C-H bond cleavages on alkylbenzenes producing the 5,7-diisopropyl-1,3,3-trimethylindan-1- yl cation from 1,3,5-triisopropylbenzene, and the 9,10-dihydro-9-anthryl cation from both 1,2,4,5-tetramethylbenzene and 1,2,3,5-tetramethylbenzene both having TaCl6- as a counteranion, and they have been characterized by X-ray analysis.

Carbocations Forming from the Reaction of Alkylbenzenes with TaCl5–CH2Cl2: Isolation and X-Ray Structures / E., Solari; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1991), pp. 841-843. [10.1039/C39910000841]

Carbocations Forming from the Reaction of Alkylbenzenes with TaCl5–CH2Cl2: Isolation and X-Ray Structures

RIZZOLI, Corrado
1991-01-01

Abstract

Tantalum pentachloride-methylene chloride system performs C-C and C-H bond cleavages on alkylbenzenes producing the 5,7-diisopropyl-1,3,3-trimethylindan-1- yl cation from 1,3,5-triisopropylbenzene, and the 9,10-dihydro-9-anthryl cation from both 1,2,4,5-tetramethylbenzene and 1,2,3,5-tetramethylbenzene both having TaCl6- as a counteranion, and they have been characterized by X-ray analysis.
1991
Carbocations Forming from the Reaction of Alkylbenzenes with TaCl5–CH2Cl2: Isolation and X-Ray Structures / E., Solari; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1991), pp. 841-843. [10.1039/C39910000841]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2313496
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