The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen-zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.
The pi and sigma Bonding Modes of meso-Octaethylporphyrinogen to Transition Metals: the X-Ray Structure of a meso-Octaethylporphyrinogen-Zirconium(IV) Complex and of the Parent meso-Octaethylporphyrinogen Ligand / D., J., C., F., A., C.V., Rizzoli, C.. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1991), pp. 790-792. [10.1039/C39910000790]
The pi and sigma Bonding Modes of meso-Octaethylporphyrinogen to Transition Metals: the X-Ray Structure of a meso-Octaethylporphyrinogen-Zirconium(IV) Complex and of the Parent meso-Octaethylporphyrinogen Ligand
RIZZOLI, Corrado
1991-01-01
Abstract
The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen-zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.File in questo prodotto:
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