The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen-zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.
The pi and sigma Bonding Modes of meso-Octaethylporphyrinogen to Transition Metals: the X-Ray Structure of a meso-Octaethylporphyrinogen-Zirconium(IV) Complex and of the Parent meso-Octaethylporphyrinogen Ligand / D., Jacoby; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1991), pp. 790-792. [10.1039/C39910000790]
The pi and sigma Bonding Modes of meso-Octaethylporphyrinogen to Transition Metals: the X-Ray Structure of a meso-Octaethylporphyrinogen-Zirconium(IV) Complex and of the Parent meso-Octaethylporphyrinogen Ligand
RIZZOLI, Corrado
1991-01-01
Abstract
The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen-zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
