Deviations from planar trigonal geometry of the dimethylamino group and from coplanarity of the benzene ring are observed in (II) and (III), where the steric hindrance between the substituents on the phenyl group is considerable.
Conformational Study on 4-(Dimethylamino)methanesulfonanilides. 1. Structures of 2-Methansulfonyl- (I), 3-Methansulfonyl- (II) and 2-Methansulfonyl-3-methyl-4-(dimethylamino)methanesulfonanilide (III) / Rizzoli, Corrado; Sgarabotto, Paolo; Ugozzoli, Franco; L., Cardellini; L., Greci; P., Stipa. - In: ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS. - ISSN 0108-2701. - C46:(1990), pp. 2118-2121. [10.1107/S0108270190000762]
Conformational Study on 4-(Dimethylamino)methanesulfonanilides. 1. Structures of 2-Methansulfonyl- (I), 3-Methansulfonyl- (II) and 2-Methansulfonyl-3-methyl-4-(dimethylamino)methanesulfonanilide (III)
RIZZOLI, Corrado;SGARABOTTO, Paolo;UGOZZOLI, Franco;
1990-01-01
Abstract
Deviations from planar trigonal geometry of the dimethylamino group and from coplanarity of the benzene ring are observed in (II) and (III), where the steric hindrance between the substituents on the phenyl group is considerable.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
