A chiral hydrophilic environment is created at either rim of calix[4]arene by the synthesis of glycosyl derivatives such as the water-soluble tetragalactosyl calixarene 1. This derivative is potentially an attractive synthetic receptor for chiral recognition of polar organic molecules.
Sugar Calixarenes: Preparation of Calix[4]arenes Substituted at the Lower and Upper Rims with O-Glycosyl Groups / A., Marra; M. C., Scherrmann; A., Dondoni; Casnati, Alessandro; P., Minari; Ungaro, Rocco. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - 33:(1994), pp. 2479-2481. [10.1002/anie.199424791]
Sugar Calixarenes: Preparation of Calix[4]arenes Substituted at the Lower and Upper Rims with O-Glycosyl Groups
CASNATI, Alessandro;UNGARO, Rocco
1994-01-01
Abstract
A chiral hydrophilic environment is created at either rim of calix[4]arene by the synthesis of glycosyl derivatives such as the water-soluble tetragalactosyl calixarene 1. This derivative is potentially an attractive synthetic receptor for chiral recognition of polar organic molecules.File in questo prodotto:
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