NMR spectroscopic studies show that Tryller's and Schmitz's compounds have furoxan (3) and 1,4,2,5‐dioxadiazine (11) structures, respectively. Combined NMR spectroscopy and X‐ray crystallography show that the products obtained by action of dinitrogen tetroxide and 5% sodium hydroxide on Tryller's compound have furazano[3,4‐d]pyridazine 1,5,6‐trioxide and furazano[3,4‐d]pyridazine 5,6‐dioxide structures 5 and 8, respectively. They also show that the product obtained by action of dinitrogen tetroxide on Schmitz's compound has a dinitroethyl‐1,4,2,5‐dioxadiazine structure 12.

A Structural Study of Tryller's and Schmitz's Compounds and Related Substances / R., Fruttero; B., Ferrarotti; A., Gasco; Calestani, Gianluca; Rizzoli, Corrado. - In: LIEBIGS ANNALEN DER CHEMIE. - ISSN 0170-2041. - (1988), pp. 1017-1023. [10.1002/jlac.198819881102]

A Structural Study of Tryller's and Schmitz's Compounds and Related Substances

CALESTANI, Gianluca;RIZZOLI, Corrado
1988

Abstract

NMR spectroscopic studies show that Tryller's and Schmitz's compounds have furoxan (3) and 1,4,2,5‐dioxadiazine (11) structures, respectively. Combined NMR spectroscopy and X‐ray crystallography show that the products obtained by action of dinitrogen tetroxide and 5% sodium hydroxide on Tryller's compound have furazano[3,4‐d]pyridazine 1,5,6‐trioxide and furazano[3,4‐d]pyridazine 5,6‐dioxide structures 5 and 8, respectively. They also show that the product obtained by action of dinitrogen tetroxide on Schmitz's compound has a dinitroethyl‐1,4,2,5‐dioxadiazine structure 12.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11381/2313364
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 22
  • ???jsp.display-item.citation.isi??? 21
social impact