Analysis of Photoinduced Birefringence in Azo-Dye Doped Films by a Fast Imaging Technique

In photobirefringent films, the relationship ρ(I) between optical retardation ρ and pump irradiance I may be obtained with imaging techniques applied within a pump-probe setup. However, measurement of ρ(I) are reported only at long irradn. times and low time-resoln. In this paper the authors describe a polariscopic imaging technique with higher sensitivity (by a factor of ∼ 30), where the probe beam is focused on the entrance pupil of the camera ("Maxwellian view"). The technique is applied to an azo-dye doped polymeric film, obtaining the continuous ρ(I) curve after irradn. times from 10 ms to 240 ms. Exponential functions are fitted against the exptl. data both as a function of time and irradiance.