An anionic Pd15-oxo-cluster [Pd15(l3-SeO3)10(l3-O)10Na]9- has been synthesized. It is the result of an unprecedented selfassembly of Pd2+ and Na+ cations, SeO3 2- and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.
Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9- and their supramolecular pairing in the solid state / M., Delferro; Graiff, Claudia; Elviri, Lisa; Predieri, Giovanni. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 39:(2010), pp. 4479-4481. [10.1039/b927537a]
Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ3-SeO3)10(μ3-O)10Na]9- and their supramolecular pairing in the solid state
GRAIFF, Claudia;ELVIRI, Lisa;PREDIERI, Giovanni
2010-01-01
Abstract
An anionic Pd15-oxo-cluster [Pd15(l3-SeO3)10(l3-O)10Na]9- has been synthesized. It is the result of an unprecedented selfassembly of Pd2+ and Na+ cations, SeO3 2- and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.| File | Dimensione | Formato | |
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