We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P=O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C4 symmetry
Formation of tetrameric water clusters driven by a cavitand template / Massera, Chiara; Melegari, Monica; Ugozzoli, Franco; Dalcanale, Enrico. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 46:(2010), pp. 88-90. [10.1039/b917931c]
Formation of tetrameric water clusters driven by a cavitand template
MASSERA, Chiara;MELEGARI, Monica;UGOZZOLI, Franco;DALCANALE, Enrico
2010-01-01
Abstract
We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P=O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C4 symmetryFile in questo prodotto:
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