An unexpected discovery in fullerene chemistry has been the ease with which C60 units can covalently bond together to give rise to polymerized fullerene networks with a variety of structural architectures. Here we report that when we probed the structural properties of Li4C60 by high-resolution synchrotron X-ray diffraction, we found that it indeed adopts a layered polymeric structure.
Li4C60: A Polymeric Fulleride with a Two-Dimensional Architecture and Mixed Interfullerene Bonding Motifs / Margadonna, S.; Pontiroli, Daniele; Belli, Matteo; Shiroka, Toni; Ricco', Mauro; Brunelli, M.. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 126:(2004), pp. 15032-15033. [10.1021/ja044838o]
Li4C60: A Polymeric Fulleride with a Two-Dimensional Architecture and Mixed Interfullerene Bonding Motifs
PONTIROLI, Daniele;BELLI, Matteo;SHIROKA, Toni;RICCO', Mauro;
2004-01-01
Abstract
An unexpected discovery in fullerene chemistry has been the ease with which C60 units can covalently bond together to give rise to polymerized fullerene networks with a variety of structural architectures. Here we report that when we probed the structural properties of Li4C60 by high-resolution synchrotron X-ray diffraction, we found that it indeed adopts a layered polymeric structure.| File | Dimensione | Formato | |
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