A comparative study concerning the electronic structure of the Mn(5+) ion in the Li(3)PO(4), Ca(2)PO(4)Cl, Sr(5)(PO(4))(3)Cl host lattices has been carried out in the framework of the exchange charge model. The crystal field parameters have been evaluated using the structural data as the only input information. The 10 K absorption spectra of the investigated compounds have been measured in order to verify the correspondence between experimental and calculated energy levels. A systematic trend of the crystal field splitting of the most intense transitions has been evidenced and discussed by considering the symmetry properties of the coordination polyhedra around Mn(5+).
Crystal field parameters and energy level structure of the MnO43- tetroxoanion in Li3PO4, Ca2PO4Cl and Sr5(PO4)3Cl crystals / M. G., Brik; Cavalli, Enrico; Borromei, Renato; M., Bettinelli. - In: JOURNAL OF LUMINESCENCE. - ISSN 0022-2313. - 129:(2009), pp. 801-806. [10.1016/j.jlumin.2009.02.018]
Crystal field parameters and energy level structure of the MnO43- tetroxoanion in Li3PO4, Ca2PO4Cl and Sr5(PO4)3Cl crystals
CAVALLI, Enrico
;BORROMEI, Renato;
2009-01-01
Abstract
A comparative study concerning the electronic structure of the Mn(5+) ion in the Li(3)PO(4), Ca(2)PO(4)Cl, Sr(5)(PO(4))(3)Cl host lattices has been carried out in the framework of the exchange charge model. The crystal field parameters have been evaluated using the structural data as the only input information. The 10 K absorption spectra of the investigated compounds have been measured in order to verify the correspondence between experimental and calculated energy levels. A systematic trend of the crystal field splitting of the most intense transitions has been evidenced and discussed by considering the symmetry properties of the coordination polyhedra around Mn(5+).| File | Dimensione | Formato | |
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