The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less polar carboxylate into the hydrophobic pocket of the metallacrown scaffold.
Thermodynamics of binding of carboxylates to amphiphilic Eu3+/Cu2+ metallacrown / Tegoni, Matteo; Tropiano, M; Marchio', Luciano. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 34:(2009), pp. 6705-6708. [10.1039/B911512A]
Thermodynamics of binding of carboxylates to amphiphilic Eu3+/Cu2+ metallacrown
TEGONI, Matteo;MARCHIO', Luciano
2009-01-01
Abstract
The binding constants of acetate and benzoate to a Pheha-based 15-metallacrown-5 have been determined by a fluorimetric indicator displacement assay demonstrating on a thermodynamic basis the stabilization effect arising from complexation of the less polar carboxylate into the hydrophobic pocket of the metallacrown scaffold.File in questo prodotto:
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