The synthesis and the crystal structures of several 4-pyridyl imino compounds are reported. Their solid state organization is based on head-to-tail chains sustained by O–H/N hydrogen bonds; the supramolecular arrangement is analysed by means of the Hirshfeld surfaces and of the corresponding 2D-fingerprint plots. The co-crystallization between 4-aminobenzyl alcohol and 4-acetylpyridine is analysed, correlating reactivity trends and structural characters. In this context, the single crystal X-ray diffraction analyses of 4-aminobenzyl alcohol and 3,5-diphenyl-4-hydroxyaniline are also reported.

A discussion on the solid state organization of 4-pyridyl imino compounds and on the co-crystallization between their molecular precursors / Bacchi, Alessia; Carcelli, Mauro; Chiodo, Tiziana; G., Cantoni; C., DE FILIPPO; S., Pipolo. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 11:(2009), pp. 1433-1441. [10.1039/b821909e]

A discussion on the solid state organization of 4-pyridyl imino compounds and on the co-crystallization between their molecular precursors

BACCHI, Alessia;CARCELLI, Mauro;CHIODO, Tiziana;
2009-01-01

Abstract

The synthesis and the crystal structures of several 4-pyridyl imino compounds are reported. Their solid state organization is based on head-to-tail chains sustained by O–H/N hydrogen bonds; the supramolecular arrangement is analysed by means of the Hirshfeld surfaces and of the corresponding 2D-fingerprint plots. The co-crystallization between 4-aminobenzyl alcohol and 4-acetylpyridine is analysed, correlating reactivity trends and structural characters. In this context, the single crystal X-ray diffraction analyses of 4-aminobenzyl alcohol and 3,5-diphenyl-4-hydroxyaniline are also reported.
A discussion on the solid state organization of 4-pyridyl imino compounds and on the co-crystallization between their molecular precursors / Bacchi, Alessia; Carcelli, Mauro; Chiodo, Tiziana; G., Cantoni; C., DE FILIPPO; S., Pipolo. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 11:(2009), pp. 1433-1441. [10.1039/b821909e]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2293413
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