crystal structure
In the title compound, (C6H8NO)(3)[SnCl6]Cl center dot 3H(2)O, the asymmetric unit contains three independent cations of protonated o-aminophenol, one hexachlorostannate(IV) and one chloride anion, and three molecules of water. The crystal structure can be described as double layers of [SnCl6] octahedra and 2-hydroxyanilinium cations parallel to the ( 10 (1) over bar) plane, with the chloride ions and the water molecules sandwiched between the double layers. A myriad of hydrogen bonds, namely, cation-cation, cation-anion, cation-water and water-water, result in a complex network of intermolecular bonds reinforcing the cohesion of the ionic structure.
Tris(2-hydroxyanilinium) hexachlorostannate(IV) chloride trihydrate / Bouacida, S; Merazig, H; Benard-Rocherulle, P; Rizzoli, C.. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - E63:(2007), pp. m379-m381. [10.1107/S160053680605656X]
Tris(2-hydroxyanilinium) hexachlorostannate(IV) chloride trihydrate
RIZZOLI C.
2007-01-01
Abstract
In the title compound, (C6H8NO)(3)[SnCl6]Cl center dot 3H(2)O, the asymmetric unit contains three independent cations of protonated o-aminophenol, one hexachlorostannate(IV) and one chloride anion, and three molecules of water. The crystal structure can be described as double layers of [SnCl6] octahedra and 2-hydroxyanilinium cations parallel to the ( 10 (1) over bar) plane, with the chloride ions and the water molecules sandwiched between the double layers. A myriad of hydrogen bonds, namely, cation-cation, cation-anion, cation-water and water-water, result in a complex network of intermolecular bonds reinforcing the cohesion of the ionic structure.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
