The 2:1 reaction of [Ru(H2O)2(NH3)5]2+ with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)5}2(μ-tz-N1:N4)]4+. Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.
μ-1,2,4,5-Tetrazine-N1:N4-bis(pentaammineruthenium) Tetracation: Synthesis and X-ray Structure / Tampucci, S; Ferrari, Marisa; Calucci, L; Pelosi, Giorgio; Denti, G.. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 360:(2007), pp. 2814-2818. [10.1016/j.ica.2006.12.044]
μ-1,2,4,5-Tetrazine-N1:N4-bis(pentaammineruthenium) Tetracation: Synthesis and X-ray Structure
FERRARI, Marisa;PELOSI, Giorgio;
2007-01-01
Abstract
The 2:1 reaction of [Ru(H2O)2(NH3)5]2+ with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)5}2(μ-tz-N1:N4)]4+. Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.File in questo prodotto:
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