In the clusters [Ru3(m3-NPPh3)(m3-OSiMe3)(m-X)(mC,OOC LNPPh3)(m-CO)(CO)6] (X = NCO, 2; X = Cl, 3), which were prepared by a pyrolytic reaction of Ph3PNSiMe3 with Ru3(CO)12, the ligands result from a cluster-mediated pseudo- Hofmann rearrangement involving the m-NCO, m(C,O)- Ph3PLN–CO and m3-NPPh3 fragments.
Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster / Belletti, Daniele; Braunstein, P.; Messaoudi, A.; Pattacini, Roberto; Predieri, Giovanni; Tiripicchio, Antonio. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - -:(2007), pp. 141-143. [10.1039/b611338a]
Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster
BELLETTI, Daniele;PATTACINI, Roberto;PREDIERI, Giovanni;TIRIPICCHIO, Antonio
2007-01-01
Abstract
In the clusters [Ru3(m3-NPPh3)(m3-OSiMe3)(m-X)(mC,OOC LNPPh3)(m-CO)(CO)6] (X = NCO, 2; X = Cl, 3), which were prepared by a pyrolytic reaction of Ph3PNSiMe3 with Ru3(CO)12, the ligands result from a cluster-mediated pseudo- Hofmann rearrangement involving the m-NCO, m(C,O)- Ph3PLN–CO and m3-NPPh3 fragments.File in questo prodotto:
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