Two new coordination cages 1a,b were prepared via metal-directed self-assembly of the tetrakis(benzonitrile) cavitands 2a,b with Pt(dppp)(CF3SO3)2. Their large portals allow fast exchange on the NMR timescale of encapsulated counterions or guests with solvent molecules.
Enlarged Cavitand-Based Coordination Cages / N., Cuminetti; M. H. K., Ebbing; P., Prados; J., DE MENDOZA; Dalcanale, Enrico. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 42:(2001), pp. 527-530. [10.1016/S0040-4039(00)01991-2]
Enlarged Cavitand-Based Coordination Cages
DALCANALE, Enrico
2001-01-01
Abstract
Two new coordination cages 1a,b were prepared via metal-directed self-assembly of the tetrakis(benzonitrile) cavitands 2a,b with Pt(dppp)(CF3SO3)2. Their large portals allow fast exchange on the NMR timescale of encapsulated counterions or guests with solvent molecules.File in questo prodotto:
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