Two new coordination cages 1a,b were prepared via metal-directed self-assembly of the tetrakis(benzonitrile) cavitands 2a,b with Pt(dppp)(CF3SO3)2. Their large portals allow fast exchange on the NMR timescale of encapsulated counterions or guests with solvent molecules.

Enlarged Cavitand-Based Coordination Cages / N. CUMINETTI; M. H.K. EBBING; P. PRADOS; J. DE MENDOZA; DALCANALE E.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 42(2001), pp. 527-530. [10.1016/S0040-4039(00)01991-2]

Enlarged Cavitand-Based Coordination Cages

DALCANALE, Enrico
2001

Abstract

Two new coordination cages 1a,b were prepared via metal-directed self-assembly of the tetrakis(benzonitrile) cavitands 2a,b with Pt(dppp)(CF3SO3)2. Their large portals allow fast exchange on the NMR timescale of encapsulated counterions or guests with solvent molecules.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11381/1452443
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