Two organic synthetic reactions - mononitration and phosphorylation of crown-6 compounds were performed under Cs+ cation monitoring via in situ complexation using electrospray ionization mass spectrometry (ESI-MS). Formation of Cs+ complexes is a rapid analytical tool for characterization of complex reaction mixtures.
Nitration of Calixcrown 6 Influence on Extracting Abilities. Use of Cesium Salts for Detection of Crown Ether Macrocycles with the Electrospray Ionization Mass Spectrometry Technique / Jankowski, C. K.; Dozol, J. F.; Allain, F.; Tabet, J. C.; Ungaro, Rocco; Casnati, Alessandro; Vicens, J.; Asfari, A.; Boivin, J.. - In: POLISH JOURNAL OF CHEMISTRY. - ISSN 0137-5083. - 76:(2002), pp. 701-709.
Nitration of Calixcrown 6 Influence on Extracting Abilities. Use of Cesium Salts for Detection of Crown Ether Macrocycles with the Electrospray Ionization Mass Spectrometry Technique
UNGARO, Rocco;CASNATI, Alessandro;
2002-01-01
Abstract
Two organic synthetic reactions - mononitration and phosphorylation of crown-6 compounds were performed under Cs+ cation monitoring via in situ complexation using electrospray ionization mass spectrometry (ESI-MS). Formation of Cs+ complexes is a rapid analytical tool for characterization of complex reaction mixtures.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
