The complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li(OtBu), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by â-hydrogen elimination or disproportionation processes under mild conditions.
Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes / Campora, Juan; Matas, Inmaculada; Palma, Pilar; Graiff, Claudia; Tiripicchio, Antonio. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 24:(2005), pp. 2827-2830. [10.1021/om0489709]
Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes
GRAIFF, Claudia;TIRIPICCHIO, Antonio
2005-01-01
Abstract
The complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li(OtBu), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by â-hydrogen elimination or disproportionation processes under mild conditions.| File | Dimensione | Formato | |
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