The two complexes [Ag(LOH)2]BF4 and [Ag(LOH)2]PF6 are synthesised by reacting a-(4-pyridyl)benzhydrol (LOH) with [Ag(CH3CN)4]BF4 and AgPF6, respectively. Their solid state arrangements are reported and analyzed. The two structures are based on the combination of coordination bonds and non-covalent interactions. The silver ions are coordinated by two pyridine rings giving the wheel-and-axle Ag(LOH)2 1 complex; the anions bridge the cations by means of hydrogen bonds with the OH groups: the result is a hybrid organic/inorganic hydrogen bonded network. A hierarchy in the importance and robustness of the supramolecular motifs observed in the two compounds is established, and the structural role of the anions is discussed.

Deconvolution of supramolecular tectons and analysis of the structural role of the anions for two "wheel-and-axle" silver complexes / Rogolino, Dominga; Bacchi, Alessia; Bosetti, E.; Carcelli, Mauro; Pelagatti, Paolo. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 6(31):(2004), pp. 177-183. [10.1039/b405940a]

Deconvolution of supramolecular tectons and analysis of the structural role of the anions for two "wheel-and-axle" silver complexes

ROGOLINO, Dominga;BACCHI, Alessia;CARCELLI, Mauro;PELAGATTI, Paolo
2004-01-01

Abstract

The two complexes [Ag(LOH)2]BF4 and [Ag(LOH)2]PF6 are synthesised by reacting a-(4-pyridyl)benzhydrol (LOH) with [Ag(CH3CN)4]BF4 and AgPF6, respectively. Their solid state arrangements are reported and analyzed. The two structures are based on the combination of coordination bonds and non-covalent interactions. The silver ions are coordinated by two pyridine rings giving the wheel-and-axle Ag(LOH)2 1 complex; the anions bridge the cations by means of hydrogen bonds with the OH groups: the result is a hybrid organic/inorganic hydrogen bonded network. A hierarchy in the importance and robustness of the supramolecular motifs observed in the two compounds is established, and the structural role of the anions is discussed.
2004
Deconvolution of supramolecular tectons and analysis of the structural role of the anions for two "wheel-and-axle" silver complexes / Rogolino, Dominga; Bacchi, Alessia; Bosetti, E.; Carcelli, Mauro; Pelagatti, Paolo. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 6(31):(2004), pp. 177-183. [10.1039/b405940a]
File in questo prodotto:
File Dimensione Formato  
cryst. eng. comm. 2004.pdf

non disponibili

Tipologia: Documento in Post-print
Licenza: Creative commons
Dimensione 594.35 kB
Formato Adobe PDF
594.35 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/1442871
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 22
  • ???jsp.display-item.citation.isi??? 21
social impact