Through the design of an optimised catalytic system for the semi-reduction of internal alkynes to cis-alkenes we showed that [Pd3]+ clusters with delocalized metal-metal bonds deliver desired products with complete selectivity and very low catalyst loadings (0.03 mol%).

Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS) / Maestri, Giovanni; Malacria, Max. - 45:(2016), pp. 16048-16048.

Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS)

MAESTRI, Giovanni;
2016-01-01

Abstract

Through the design of an optimised catalytic system for the semi-reduction of internal alkynes to cis-alkenes we showed that [Pd3]+ clusters with delocalized metal-metal bonds deliver desired products with complete selectivity and very low catalyst loadings (0.03 mol%).
2016
Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS) / Maestri, Giovanni; Malacria, Max. - 45:(2016), pp. 16048-16048.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2822633
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