Through the design of an optimised catalytic system for the semi-reduction of internal alkynes to cis-alkenes we showed that [Pd3]+ clusters with delocalized metal-metal bonds deliver desired products with complete selectivity and very low catalyst loadings (0.03 mol%).
Titolo: | Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS) |
Autori: | |
Data di pubblicazione: | 2016 |
Handle: | http://hdl.handle.net/11381/2822633 |
Appare nelle tipologie: | 7.12 Altro |
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