Through the design of an optimised catalytic system for the semi-reduction of internal alkynes to cis-alkenes we showed that [Pd3]+ clusters with delocalized metal-metal bonds deliver desired products with complete selectivity and very low catalyst loadings (0.03 mol%).
Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS) / Maestri, Giovanni; Malacria, Max. - 45:(2016), pp. 16048-16048.
Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes Showcasing research from Prof. Maestri (UniPR) and Prof. Malacria (UPMC/CNRS)
MAESTRI, Giovanni;
2016-01-01
Abstract
Through the design of an optimised catalytic system for the semi-reduction of internal alkynes to cis-alkenes we showed that [Pd3]+ clusters with delocalized metal-metal bonds deliver desired products with complete selectivity and very low catalyst loadings (0.03 mol%).File in questo prodotto:
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