A simple synthetic method allows the one-pot assembly of C3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics / Wang, Yanlan; Deyris, Pierre Alexandre; Caneque, Tatiana; Blanchard, Florent; Li, Yanling; Bigi, Franca; Maggi, Raimondo; Blanchard, Sebastien; Maestri, Giovanni; Malacria, Max. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 21:35(2015), pp. 12271-12274. [10.1002/chem.201501239]

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics

BIGI, Franca;MAGGI, Raimondo;MAESTRI, Giovanni;
2015-01-01

Abstract

A simple synthetic method allows the one-pot assembly of C3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues
2015
A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics / Wang, Yanlan; Deyris, Pierre Alexandre; Caneque, Tatiana; Blanchard, Florent; Li, Yanling; Bigi, Franca; Maggi, Raimondo; Blanchard, Sebastien; Maestri, Giovanni; Malacria, Max. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 21:35(2015), pp. 12271-12274. [10.1002/chem.201501239]
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2795032
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 25
  • ???jsp.display-item.citation.isi??? 25
social impact