The species Ru3(H)(m3-NPPh3)(CO)9 occurs in the solid state as two isomers, characterized either by one capping hydride and three CO bridges (1a) or by one bridging hydride and all terminals COs (1b); key intermediates for the formation, fluxionality and solvent-dependent interconversion of the isomers are highlighted through a DFT MO analysis.
Experimental and computational studies on the solvent-controlled cluster isomerism of Ru3(H)(CO)9(NPPh3) and related dynamics / Pattacini, Roberto; Predieri, Giovanni; Tiripicchio, Antonio; Mealli, Carlo; PHILLIPS ANDREW, D.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - -:(2006), pp. 1527-1529. [10.1039/b516137a]
Experimental and computational studies on the solvent-controlled cluster isomerism of Ru3(H)(CO)9(NPPh3) and related dynamics
PREDIERI, Giovanni;TIRIPICCHIO, Antonio;
2006-01-01
Abstract
The species Ru3(H)(m3-NPPh3)(CO)9 occurs in the solid state as two isomers, characterized either by one capping hydride and three CO bridges (1a) or by one bridging hydride and all terminals COs (1b); key intermediates for the formation, fluxionality and solvent-dependent interconversion of the isomers are highlighted through a DFT MO analysis.| File | Dimensione | Formato | |
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